Carbofuran usage has increased in recent years because it is one of the few insecticides effective on soybean aphids, which have expanded their range since 2002 to include most soybeangrowing regions of the united states. Journal of toxicology and environmental health, part a. Carbofuran 3hydroxy7 phenol buy from the brand leader in analytical reference standards. Because of its anesthetic effects, phenol is used in medicines such as ointments, ear and nose drops, cold sore lotions, throat lozenges. Rechercher les fabricants des insecticide carbofuran produits.
The effect from exposure to carbofuran has been investigated on acetylcholinesterase ache activity in the brain and muscle of common carp cyprinus carpio. Carbofuran 100 gr material safety data sheet page 1 of 5 1. Validated by experts, validated by users, nonvalidated, removed by. The metabolites of carbofuran are less toxic than the parent compound. Phenols and cresols are much weaker as acids than common carboxylic acids phenol has pka 9. Carbofuran is mobile in soil, particularly sandy soil with high percolation rate. Buy high purity carbofuranphenol3keto analytical standards from chem service inc. Contain material far ahead of spill for later disposal. The separation of catechol from carbofuran phenol by. Kinetics of phenol, methomyl and carbofuran conversion in %, on different. Carbofuranphenol3keto analytical standards 17781167.
Carbofuran phenol, compounds in this group do not behave as organic alcohols, as one might guess from the presence of a hydroxyl oh group in their structure. Properly induced cells were able to degrade carbofuran to 7 phenol within 4 h, and to 4hydroxycarbofuran in 8 h. Central drug house p ltd 728 vardaan house new delhi2 india. The extremely high stability of carbofuran pesticide in acidic media anelka v. Material safety data sheet 4 methylaminophenol sulfate solution 2 individuals and some asthmatics. This invention relates, in general, to an improved process for the preparation of carbofuran and to certain intermediate products. Carbofuran fact sheet 2 toxicological characteristics. Accelerated degradation of carbaryl and carbofuran in a. A wide variety of carbofuran options are available to you, there are 92 suppliers who sells carbofuran on, mainly located in asia.
It was reported that there was an oxidative transformation of carbofuran to 4. Carbofuran is one of the most toxic carbamate pesticides. Causes severe skin burns and eye damage toxic if inhaled suspected of causing genetic defects may cause damage to organs through prolonged or. Phenol hydroxybenzene c6h6o 94,11 gmol concentration casno. The following is a textformat carbaryl pathway map. Carbofuran3hydroxy7phenol c10h12o3 674667 17781156. Accelerated degradation of carbaryl and carbofuran in a flooded soil pretreated with hydrolysis products, 1naphthol and carbofuran phenol. These complex analyses, when available, can be useful in identifying the responsible agent and following the course of carbamate disposition. Its uses include seed treatment, atplanting soil application, and directed or. Phenol is also used in the production of synthetic fibers such as nylon and for epoxy resin precursors such as bisphenola. Kiss environment friendly iron catalysts were applied in the decomposition reactions of some toxic compounds like phenol, methomyl and corbofuran pesticide. Carbofuran3hydroxy7phenol buy from the brand leader in analytical reference standards.
Material safety data sheet 4methylaminophenol sulfate. Identification of the chemical product and company supplier. The separation of catechol from carbofuran phenol by extractive distillation zhang jianyu m12, hu aixi tljt1 wang yu i12, xiao xuhui ft m2, guo jiabin ipx1 and luo xianfu j. Identification of the substancemixture and of the companyundertaking product name. Carbofuran is a carbamate ester and a member of 1benzofurans. Carbofuran has a moderate rate of degradation in soil halflife 50 days. Show this safety data sheet to the doctor in attendance. S 1 college of chemistry and chemical engineering, hunan university, changsha 410082, china 2 hunan haili chemical industry co. Process for the preparation of carbofuran union carbide. Phenol is a colorless or white solid when it is pure. Epa plans new use limitations on carbaryl, carbofuran, and methomyl to protect salmon and steelhead in california, idaho, oregon, and washington pdf 20 pp, 888. Among the metabolites assayed was 4hydroxy carbofuran.
Carbofuran may also be hydroxylated at the 5 position by novosphingobium sp. Purchase online carbofuranphenol drec11012100 cas number 1563388. Rechercher les fabricants des insecticide carbofuran. It was reported that there was an oxidative transformation of carbofuran to 4hydroxy carbofuran and a hydrolytic conversion by pseudomonas sp. The agency intended to cancel all uses of carbofuran due to ecological and occupational risks of. Fungal degradation of carbofuran may occur via hydroxylation at the three position and oxidation to 3ketocarbofuran salama et al. Its uses include seed treatment, atplanting soil application, and directed or foliar applications. It is a systemic insecticide, which means that the plant absorbs it through the roots, and from there. Pdf fungal biodegradation of carbofuran and carbofuran. In august 2006, epa published its carbofuran interim reregistration eligibility decision ired pdf 44 pp, 392k, about pdf concluding that no carbofuran uses met the statutory standards, and therefore no uses were eligible for reregistration. Identification of the substancepreparation and of the companyundertaking product name phenol unid no un1671 synonyms phenol molecular weight 94.
Sigmaaldrich offers a number of carbofuran products. The major degradates of concern are the 3hydroxy carbamate and 7phenol products resulting from hydrolysis. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. It is used to control insects in a wide variety of field crops, including potatoes, corn and soybeans. Carbofuran is an anticholinesterase carbamate, which is commonly used as a pesticide. Validated by experts, validated by users, nonvalidated, removed by users. Sweep up with sand or other suitable absorbent material and place into containers for later disposal. If inhaled if breathed in, move person into fresh air. Material safety data sheet 4methylaminophenol sulfate solution.
In one aspect this invention is directed to a simple, two step process for preparing carbofuran phenol from relatively inexpensive materials. It undergoes rapid hydrolysis under alkaline high ph conditions, but is stable at acidic low ph. Treatment of nmethyl carbamate insecticide toxicosis. Fungal biodegradation of carbofuran and carbofuran phenol by the fungus mucor ramannianus. Carbofuran 10 gr msds arysta lifescience south africa. Phenol material safety data sheet cas no 108952 sdsmsds. It is marketed under the trade names furadan, by fmc corporation and curaterr 10 gr, by bayer, among several others. Phenol, 5% wv safety data sheet according to federal register vol. Besides, a saturation phenomenon was observed in the presence of pillared interlayered clay catalyst. Phenol sara 3 toxic chemical notification and release. Neutralise with sodium hydroxide and allow standingfor 4 hours. Phenol is toxic to bacteria and fungi, and it is used as a slimicide and disinfectant. Safety data sheet according to 29cfr19101200 and ghs rev. Purchase online carbofuran phenol drec11012100 cas number 1563388.